What is the half-equation for the reaction of MnO4- ions with H2O2?

Study for the Electrochemical Exam. Learn with flashcards and multiple-choice questions, each question with hints and explanations. Get well-prepared and confident for your exam!

The half-equation for the reaction of MnO4- ions with H2O2 can indeed encompass various forms depending on the context of the reaction, particularly when considering the overall redox process involving both the permanganate ion and hydrogen peroxide.

The half-equation you see involving MnO4- accepts electrons and protons, reflecting how the permanganate ion is reduced. This is captured in the second choice, where MnO4- is reduced to Mn2+, illustrating that it gains electrons in the presence of an acidic environment (shown by the presence of H+ ions). This reaction proceeds with the release of water, which balances the charges and mass in the equation.

In the case of H2O2, it acts as an oxidizing agent, which is shown in the first option, where H2O2 decomposes into oxygen gas and hydrogen ions, while losing electrons. This highlights the oxidation half-reaction that occurs simultaneously with the reduction of MnO4-.

The third option presents a complete redox reaction where both MnO4- and H2O2 are involved. In this overall reaction, the molar proportions indicate how two moles of permanganate react with hydrogen peroxide under acidic conditions to produce

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