Which reaction has a standard electrode potential of +1.33 V?

Study for the Electrochemical Exam. Learn with flashcards and multiple-choice questions, each question with hints and explanations. Get well-prepared and confident for your exam!

The reaction with a standard electrode potential of +1.33 V is correctly identified as the one involving the reduction of chromium from its hexavalent state in dichromate to the trivalent state. This reduction reaction, which includes the transfer of electrons alongside protons, culminates in the formation of Cr³⁺ ions and water. The high positive value of the standard electrode potential indicates that this reaction is strongly favorable under standard conditions, meaning it can occur easily and is a good oxidizing agent.

In electrochemical terms, a higher standard electrode potential implies a greater tendency to be reduced. For this particular reaction, the involvement of multiple electrons (6 in total) and acidic conditions (indicated by the presence of H⁺ ions) plays a significant role in stabilizing the products and facilitating the reaction, contributing to the measured electrode potential.

The other reactions listed do not possess this specific high positive value but instead correspond to different standard electrode potentials. For instance, while the reaction involving bromine is also a strong oxidizer, it has a lower standard electrode potential compared to that of chromium in its dichromate state. Similarly, the other reactions involving iron and silver have their own characteristic potentials, but neither reaches the elevated level achieved by the

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